Objective: The research focused on Williamson's nonlinear governing flow on Magneto hydrodynamic incompressible, steady fluid over a porous stretching sheet in a two-dimensional direction. The permeable stretching sheet embedded by Williamson fluid is based on the flow model of non-Darcy Forchheimer law with chemical reaction. This article concentrated on an energy equation dominated by the dissipation parameter analysis. Methods: The governing mathematical partial derivative formulations are changed to a system of ordinary differential formulations with appropriate similarity transformation. The mathematical formulations are evaluated employing the numerical method of the R-K fourth-order scheme. MATLAB software bvp4c is used for computing numerical results. The numerical results and graphs were successfully demonstrated with the R-K fourth-order system. Findings: For the influence of Williamson non-Newtonian, non-fluid observed emerging dimensionless quantifiers such as Williamson number, porous, electric, thermophoresis, Brownian motion, Prandtl, and Schmidt dimensionless number respectively. The performance of non-dimensional parameters is investigated in detail. Novelty: As described in the results, Williamson's non-Newtonian nanofluid under the influence of magneto-hydrodynamics is mentioned as a new value to the existing literature. The gained results are the innovative study of the influence of chemical reaction on Williamson non-Newtonian nanofluid and magnetic strength and reported on dimensionless parameters. Keywords: Electric parameter, Williamson Nanofluid, Darcy-Forchheimer, Viscous dissipation, Chemical reaction quantifier