2014
DOI: 10.1007/s00723-014-0541-7
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Three-Pulse ELDOR Theory Revisited

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Cited by 49 publications
(36 citation statements)
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“…EPR spectroscopy can be employed to measure spin–spin distances in bis‐labeled molecules (peptides). To explore peptide length variations that were possibly associated with the observed conformational switch, two bis‐labeled trichogin analogues, namely, T18‐ol and T18‐OMe (Table ), were synthesized and analyzed by means of CW and pulsed EPR spectroscopy (see the Supporting Information) . A screw‐sense inversion should not change the peptide length significantly.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…EPR spectroscopy can be employed to measure spin–spin distances in bis‐labeled molecules (peptides). To explore peptide length variations that were possibly associated with the observed conformational switch, two bis‐labeled trichogin analogues, namely, T18‐ol and T18‐OMe (Table ), were synthesized and analyzed by means of CW and pulsed EPR spectroscopy (see the Supporting Information) . A screw‐sense inversion should not change the peptide length significantly.…”
Section: Resultsmentioning
confidence: 99%
“…The normalized pair, V n ( T ), time traces were obtained from Equation (2) and Fourier transformation was performed. The multi‐Gaussian Monte‐Carlo fitting was performed by using the homemade program in Pascal.NET software . Three Gaussians were enough to attain good agreement with experimental PELDOR data (see the Supporting Information).…”
Section: Methodsmentioning
confidence: 99%
“…Recent developments of the theory of the PELDOR method include the use of more accurate theoretical formulas for the analysis of the experimental results. Newly proposed aspects of a sophisticated PELDOR theory take into account the interaction between spin labels in pairs or aggregates when the EPR spectra of spins A and B overlap or coincide. In this case, corrections for theoretically calculated p b values are needed.…”
Section: Peldor Spectroscopymentioning
confidence: 99%
“…Accordingly, some spin partners within the studied ensemble are excited non-selectively by either pump or observation pulses. The resulting multitude of residual dipolar evolution pathways has been analyzed recently 11 . For non-selective excitation pulses, as used in DQC and SIFTER, the width of the coupled spins' EPR spectra often exceeds the excitation bandwidth attainable with monochromatic pulses.…”
Section: Introductionmentioning
confidence: 99%