Three-sublattice model that takes into account the spin density anisotropy, short-range order, and dimensioned factor for the binary Fe-Cr(V, Mo) systems
“…14 was obtained as a result. On base of this ground the system of the equations was obtained for a search of initial parameters of model at 0K.…”
Section: Calculation Methodsmentioning
confidence: 99%
“…Especially there is an open question of establishment of influence of static mixtures on magnetic properties of the atoms located in five sublattices of sigma -phase, and on the average magnetic moment depending on structure. Though the first steps in this direction was make and partially theoretically solution were obtained in paper [14] for ferromagnetic BCC -phases as well of pure iron as of the Fe-Cr alloys.…”
Section: The Model Formulation For -Phasementioning
confidence: 99%
“…The Gibbs free energy of mixing of s-phase of alloys with regard to s-phases of both components according to 3SLM is equal (the details of the mathematical calculations possible to see in paper [14]):…”
Section: The Model Formulation For -Phasementioning
The three- sub-lattice model (3SLM) for description of atom’s distribution of two components with different coordination numbers (12, 14 and 15), into s-phase structure depended on composition and temperature is depictured in this paper. Energetic parameters of 3SLM were calculated by fitting procedure fixed to results obtained by ab-initio calculations conducted for paramagnetic states of differently ordered complexes stayed at the sigma-phase’s crystal structure for Fe-Cr system at 0 K. Respective algorithm and computer program have allowed to calculate an atom distribution of components upon the sub-lattices of s-phase at 300 - 1100 K. There is satisfactory agreement between calculated results and the experimental data obtained by neutron and structural research methods. Obtained results demonstrate satisfactory agreement between calculated and experimental data of BCC solutions and sigma - phase of the Fe-Cr system stayed at an equilibrium state
“…14 was obtained as a result. On base of this ground the system of the equations was obtained for a search of initial parameters of model at 0K.…”
Section: Calculation Methodsmentioning
confidence: 99%
“…Especially there is an open question of establishment of influence of static mixtures on magnetic properties of the atoms located in five sublattices of sigma -phase, and on the average magnetic moment depending on structure. Though the first steps in this direction was make and partially theoretically solution were obtained in paper [14] for ferromagnetic BCC -phases as well of pure iron as of the Fe-Cr alloys.…”
Section: The Model Formulation For -Phasementioning
confidence: 99%
“…The Gibbs free energy of mixing of s-phase of alloys with regard to s-phases of both components according to 3SLM is equal (the details of the mathematical calculations possible to see in paper [14]):…”
Section: The Model Formulation For -Phasementioning
The three- sub-lattice model (3SLM) for description of atom’s distribution of two components with different coordination numbers (12, 14 and 15), into s-phase structure depended on composition and temperature is depictured in this paper. Energetic parameters of 3SLM were calculated by fitting procedure fixed to results obtained by ab-initio calculations conducted for paramagnetic states of differently ordered complexes stayed at the sigma-phase’s crystal structure for Fe-Cr system at 0 K. Respective algorithm and computer program have allowed to calculate an atom distribution of components upon the sub-lattices of s-phase at 300 - 1100 K. There is satisfactory agreement between calculated results and the experimental data obtained by neutron and structural research methods. Obtained results demonstrate satisfactory agreement between calculated and experimental data of BCC solutions and sigma - phase of the Fe-Cr system stayed at an equilibrium state
“…Scintillators based on polystyrene and polymethyl metacrylate with different additions that shift the emanation spectrum towards waves with higher lengths are known to be the best of native scintillators [34]. PMT 30,36,87,143 are the most often used as time PMT. Pulses from detectors enter two identical channels, where the amplitude pulse selection for search of pulses according to energies 0.511 and 1.27 MeV and the time binding is made.…”
Section: Technique and Instrumentationmentioning
confidence: 99%
“…Capture constant is connected with defects parameters in the following way , where R 2,3 are the characteristic defect sizes, С is the defects concentration, D + is the positron diffusion coefficient. The type and concentration of defects can be estimated using data of ref [36]*, the positron diffusion coefficient is accepted to be 1 сm 2 /с in these calculations. The electron density in clusters can't differ more than for 2 times in comparison with electron density in vacancies, since the lifetime of positrons in vacancies is two times shorter than the lifetime of positrons in a cluster, capture of positrons taking place on the surface of the cluster.…”
Section: A Udovsky Et Al / Jmm 53 (3) B (2017) 399 -405mentioning
Properties of binary and ternary iron based alloys doped by different additions were investigated. It was shown for binary alloys containing chromium, molybdenum and tungsten were that results of doping by 0.8% molybdenum and tungsten were similar to those for the sample doped by 9%chromium. Ternary alloys containing chromium and less amounts of molybdenum, tungsten and vanadium were investigated as well. Two types of defects were observed: divacancies and cluster-like defects. It was shown that the electron density in ternary alloys is similar to that in binary alloys containing 0.8% molybdenum.
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