2017
DOI: 10.1016/j.jorganchem.2017.05.016
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TMPMg Bu(L), where L = THF, 2-MeTHF, pyridine and dimethylaminopyridine and TMP = 1,5,9-trimesityldipyrromethene: Reaction with lactide and ε-caprolactone

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Cited by 6 publications
(1 citation statement)
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“…[1][2][3][4] As a powerful strategy for the preparation of polyester, the organometallicspromoted ring-opening polymerization (ROP) of aliphatic lactones has attracted great attentions. [5][6][7][8] To date, plenty of organometallics have been demonstrated as efficient catalysts for the ROP of lactones, such as alkali metals (Li, 9 K [10][11] ), alkaline-earth metals (Mg, [12][13][14][15][16][17][18] Ca, 19 Ba 20 ), aluminum, [21][22][23][24][25] tin, 26 rare-earth metals [27][28][29][30][31][32][33][34] and some transition metals (Ti, 35 Zr, 36 V, 37 Fe, [38][39] Zn [40][41][42][43] ). Among them, the magnesium-based complex has attracted special attention due to its high activity and low toxicity.…”
Section: Introductionmentioning
confidence: 99%
“…[1][2][3][4] As a powerful strategy for the preparation of polyester, the organometallicspromoted ring-opening polymerization (ROP) of aliphatic lactones has attracted great attentions. [5][6][7][8] To date, plenty of organometallics have been demonstrated as efficient catalysts for the ROP of lactones, such as alkali metals (Li, 9 K [10][11] ), alkaline-earth metals (Mg, [12][13][14][15][16][17][18] Ca, 19 Ba 20 ), aluminum, [21][22][23][24][25] tin, 26 rare-earth metals [27][28][29][30][31][32][33][34] and some transition metals (Ti, 35 Zr, 36 V, 37 Fe, [38][39] Zn [40][41][42][43] ). Among them, the magnesium-based complex has attracted special attention due to its high activity and low toxicity.…”
Section: Introductionmentioning
confidence: 99%