2022
DOI: 10.1002/chem.202203396
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Total Synthesis, Absolute Configuration, and Phytotoxic Activity of Foeniculoxin

Abstract: Foeniculoxin is a major phytotoxin produced by Italian strains of Phomopsis foeniculi. The first total synthesis is described utilizing the ene reaction and Sonogashira crosscoupling reaction as key steps. The absolute configuration of the C6' was determined using chiral separation and an advanced Mosher's method. The phytotoxicity of the synthesized compound was demonstrated via syringe-based infiltration into Chenopodium album and Arabidopsis thaliana leaves.Synthetic foeniculoxin induced various defects in … Show more

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References 31 publications
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