“…Very recently, Gholivand et al performed DFT calculation of 2 J PC coupling constants in the series of phosphoryl benzamides, C 6 H 5 C(O)NHP(O)R 1 R 2 , with R 1 and R 2 being aziridine, azetidine, pyrrolidine, piperidine, azepane, 4‐methylpiperidine, propane‐2‐amine, and 2‐methylpropane‐2‐amine. Calculated 2 J PC couplings were in a reasonably good agreement with available experimental data, and their substituent trends were interpreted in terms of geometric and electronic properties, the latter involving atomic charge and hybridization effects on phosphorous.…”