“…22,23 At the same time, manganese dioxide has the advantages of rich reserves, low preparation cost, environmental friendliness (low toxicity), etc. 24 At present, a large number of publications have reported that manganese dioxide crystals with different particle sizes and specific morphologies can be obtained by adjusting the conditions of experimental preparation. 25 Manganese dioxide nanomaterials have complex morphological characteristics such as lines, flowers, tubes, balls, etc .…”