Recent years, the tremendous number of distributed energy resources, electric vehicles are integrated into the Low-Voltage Distribution Network (LVDN), large amount of data are generated by edge devices in LVDN. The cloud data centers are unable to process these data timely and accurately, making it impossible to meet the demand for fine-grained control of LVDN. To solve the above problems, this paper proposes a flexible orchestration of lightweight artificial intelligence (AI) for edge computing in LVDN. Firstly, the application requirements of LVDN are analysed through feature extraction of its historical data, and a lightweight AI library is constructed to meet its requirements. Secondly, based on the multi-factor priority, a flexible orchestration model is established, to allow the lightweight AI embedded in the edge devices of the LVDN. Finally, the particle swarm optimization algorithm is used to provide the best solution. The simulation results show that the method proposed in this paper can support the deployment of AI at the edge. It can significantly improve the utilization of edge computing resources, and reduce the pressure of cloud computing and the time of application processes.