2021
DOI: 10.1021/acs.inorgchem.1c00801
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Trans Element-Hydrogen Bonds: A Distinctive Difference Between Transition Metals and Main Group Elements

Abstract: The change in sign of the interaction force constant between element-hydrogen stretching modes of trans-dihydrides of the d block and p block elements is analyzed for the first time. As the transition metal M approaches group 12, the higher energy symmetric trans-H−M−H vibration ν sym approaches the energy of the antisymmetric vibration ν asym . Crossing to group 13 elements E, the trans-H−E−H vibration ν sym increasingly drops below ν asym . This reversal is attributed to the d orbital that participates in th… Show more

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