Trinuclear ruthenium clusters supported by piconol ligands: Application in catalytic C(sp3)-H bond oxidation in CH3CN/H2O

Hao, Zhiqiang; Xu, Jingxue; Dong, Qing; Xu, Hui; Ma, Zhihong; Lin, Jin; Lu, Guo-Liang

doi:10.1016/j.jorganchem.2023.122981

Journal of Organometallic Chemistry

2024

DOI: 10.1016/j.jorganchem.2023.122981

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Trinuclear ruthenium clusters supported by piconol ligands: Application in catalytic C(sp3)-H bond oxidation in CH3CN/H2O

Zhiqiang Hao,

Jingxue Xu,

Qing Dong

et al.

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Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

Xu,

Xing,

Hao

et al. 2024

Applied Organom Chemis

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Treatment of Ru3(CO)12 with salicylaldimine ligands [ArNCH(3‐tBuC6H3OH) [ArC6H5 (L1H); 4‐OMeC6H4 (L2H); 4‐MeC6H4 (L3H); 2,4,6‐Me3C6H2 (L4H); 4‐ClC6H4 (L5H); 4‐BrC6H4 (L6H)] in refluxing toluene afforded six bis‐ligand mononuclear ruthenium carbonyl complexes [ArNCH(3‐tBuC6H3O)]2Ru(CO)2 1a–1f in good yields. All of the Ru(II) complexes were characterized using IR, NMR, and elemental analysis. The molecular structures of complexes 1a, 1b, 1e, and 1f were further confirmed through X‐ray diffraction analysis. Additionally, the catalytic performance of these complexes was investigated in the oxidation of olefins to aldehydes, using TBHP as the oxidant in refluxing trichloromethane. With 1.0 mol% catalyst loading, these ruthenium complexes displayed high reactivity and good functional‐group compatibility, selectivity providing the corresponding oxidation product aldehydes in 73%–94% yields.

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Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

Xu,

Xing,

Hao

et al. 2024

Applied Organom Chemis

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Trinuclear ruthenium clusters supported by piconol ligands: Application in catalytic C(sp3)-H bond oxidation in CH3CN/H2O

Cited by 1 publication

References 31 publications

Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

Selective Oxidative Scission of Olefins to Aldehydes Enabled by Ruthenium Complexes Containing Salicylaldimine Ligands

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