Abstract:Square planar Pt(ii) terpyridine complexes with pincer ligands undergo two-electron oxidation and variation in the ligand substituents allows for tuning of the two-electron oxidation process over a 260 mV range.
Dramatic changes of secondary chirality reflecting on enhancement of chiral signals (i.e., CD and CPL) is induced through coordination-derived steric changes of terpyridyl ligand attached on glutamide-based molecular gels.
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