“…41,42 What is more surprising, while several alkylene-bridged derivatives of 4,5-diiodoimidazole were prepared and described several years ago (considered as potential biocidal agents), 43 these were not yet utilized as linkers for the design of coordination polymers, although iodine-free 1, X -bis(imidazol-1-yl)alkanes are very well known in this role – there are several hundreds of such structurally characterized MOFs. 44–50…”
The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I)...
“…41,42 What is more surprising, while several alkylene-bridged derivatives of 4,5-diiodoimidazole were prepared and described several years ago (considered as potential biocidal agents), 43 these were not yet utilized as linkers for the design of coordination polymers, although iodine-free 1, X -bis(imidazol-1-yl)alkanes are very well known in this role – there are several hundreds of such structurally characterized MOFs. 44–50…”
The new iodine-rich imidazole derivative 1,4-bis(4,5-diiodo-1H-imidazol-1-yl)butane (bimbI4, 1) features multiple I···I interactions in solid state. Using 1 as precursor, we prepared 1D and 2D coordination polymers of Co(II) and Cu(I)...
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