Two-Dimensional ENDOR-ESEEM Correlation Spectroscopy

Numerical Simulation of One- and Two-Dimensional ESEEM Experiments

“…In fact, a number of experiments (e.g., matched ESEEM (26,(46)(47)(48)(49)) benefit from the use of tailored nonideal pulses. Consequently, the effect of the nonideality of the pulses should be considered in the simulations (17,50). The time evolution during the extended mw irradiation periods (real pulses) is computed in a frame rotating with the mw frequency about the effective quantization axis of the electron spin.…”

Two-Dimensional Pulsed TRIPLE at 95 GHz

“…The two last experiments require the application of nonselective microwave pulses, which is somewhat problematic with current state of the art high field ENDOR spectrometers due to their limited microwave power. Another recent example is the ENDOR-ESEEM correlation experiment (23). In ENDOR spectroscopy, correlations between signals belonging to the same paramagnetic center and the same M S manifold can be obtained by extending the 1D pulsed TRIPLE experiment into two-dimensions, as introduced in the present work.…”