“…A possible explanation for this phenomenon could be several overlapping surface states or a conduction band pushed below the Fermi edge. For example, another allotrope of phosphorus, Black Phosphorus, has a conduction band with a minimum at the Γ point below the Fermi energy, whose shape corresponds to an upward-open parabola . If the latter is the case, the 2D material would no longer be a semiconductor but would have a metallic character.…”
Section: Resultsmentioning
confidence: 99%
“…For example, another allotrope of phosphorus, Black Phosphorus, has a conduction band with a minimum at the Γ point below the Fermi energy, whose shape corresponds to an upward-open parabola. 51 If the latter is the case, the 2D material would no longer be a semiconductor but would have a metallic character. In a recent study by Arcudia et al, it was theoretically shown that the semiconducting properties of BlueP can be replaced with metallic ones by arranging two layers of BlueP in a specific way.…”
“…A possible explanation for this phenomenon could be several overlapping surface states or a conduction band pushed below the Fermi edge. For example, another allotrope of phosphorus, Black Phosphorus, has a conduction band with a minimum at the Γ point below the Fermi energy, whose shape corresponds to an upward-open parabola . If the latter is the case, the 2D material would no longer be a semiconductor but would have a metallic character.…”
Section: Resultsmentioning
confidence: 99%
“…For example, another allotrope of phosphorus, Black Phosphorus, has a conduction band with a minimum at the Γ point below the Fermi energy, whose shape corresponds to an upward-open parabola. 51 If the latter is the case, the 2D material would no longer be a semiconductor but would have a metallic character. In a recent study by Arcudia et al, it was theoretically shown that the semiconducting properties of BlueP can be replaced with metallic ones by arranging two layers of BlueP in a specific way.…”
“…Other EPMs such as blue-P and green-P have recently also shown promising theoretical potential as electrodes in SCs. 604…”
Section: Applications Of Elemental Phosphorus Materials To Sustainabl...mentioning
confidence: 99%
“…Other EPMs such as blue-P and green-P have recently also shown promising theoretical potential as electrodes in SCs. 604 5.2.6 Other energy storage applications. Lithium-sulphur batteries (LSBs) represent a promising type of rechargeable battery with significant development potential.…”
This review summarizes the advancements in elemental phosphorus materials, focusing on fundamental physicochemical properties, synthesis, and applications in sustainable energy and environment.
“…Black phosphorus (BP) has a unique and outstanding 2D structure, and shows a signicant potential material for nextgeneration energy storage devices. 279 The material has attained signicant research attention due to its advantageous electrochemical and structural properties, such as high carrier mobility, high theoretical capacity, and low redox reactions. Due to these outstanding properties, BP is found to be a suitable anode material in LIBs.…”
Electrode materials with exceptional cyclic stability and high-rate performance have been in extensive demand for the fast growth of energy storage applications.
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