Water is often considered as the
highest performance working fluid for liquid–vapor phase change
due to its high thermal conductivity and large enthalpy of vaporization.
However, a wide range of industrial systems require using low surface
tension liquids where heat transfer enhancement has proved challenging
for boiling and evaporation. Here, we enable a new paradigm of phase
change heat transfer, which favors high volatility, low surface tension
liquids rather than water. We utilized a nanoporous membrane of ≈600
nm thickness and <140 nm pore diameters supported on efficient
liquid supply architectures, decoupling capillary pumping from viscous
loss. Proof-of-concept devices were microfabricated and tested in
a custom-built environmental chamber. We used R245fa, pentane, methanol,
isopropyl alcohol, and water as working fluids with devices of total
membrane area varying from 0.017 to 0.424 cm2. We realized
a device-level pure evaporation heat flux of 144 ± 6 W/cm2 for water, and the highest evaporation heat flux was obtained
with pentane at 550 ± 90 W/cm2. We developed a three-level
model to understand vapor dynamics near the interface and thermal
conduction within the device, which showed good agreement with experiments.
We then compared pore-level heat transfer of different fluids, where
R245fa showed approximately 10 times the performance of water under
the same working conditions. Finally, we illustrate the usefulness
of a figure of merit extracted from the kinetic theory for evaporation.
The current work provides fundamental insights into the evaporation
of low surface tension liquids, which can impact various applications
such as refrigeration and air conditioning, petroleum and solvent
distillation, and on-chip electronics cooling.