Two-Site Occupation for Constructing Double Perovskite BaLaMgNbO₆:Cr³⁺ Ultrabroadband NIR Phosphors

Abstract

Given the escalating significance of near-infrared (NIR) spectroscopy across industries, agriculture, and various domains, there is an imminent need to address the development of a novel generation of intelligent NIR light sources. Here, a series of Cr 3+doped BaLaMgNbO 6 (BLMN) ultrabroadband NIR phosphor with a coverage range of 650−1300 nm were developed. The emission peak locates at 830 nm with a full width at half maximum of 210 nm. This ultrabroadband emission originates from the 4 T 2 → 4 A 2 transition of Cr 3+ and the simultaneous occupation of [MgO 6 ] and [NbO 6 ] octahedral sites confirmed by low photoluminescence spectra (77−250 K), time-resolved photoluminescence spectra, and electron paramagnetic resonance spectra. The fluxing strategy improves the luminescence intensity and thermal stability of BLMN:0.02Cr 3+ phosphors. The internal quantum efficiency (IQE) is 51%, external quantum efficiency (EQE) can reach 33%, and thermal stability can be maintained at 60%@100 °C. Finally, we successfully demonstrated the application of BLMN:Cr 3+ ultrabroadband in the qualitative analysis of organic matter and food freshness detection.