Two Zn(II)-organic frameworks based on “V”-shaped terpyridine ligand and dicarboxylic ligands: Fascinating architectures and efficient luminescent aqueous-phase dual-responsive detection

Role of the Environment Polarity on the Photophysical Properties of Mesogenic Hetero-Polymetallic Complexes

“…2,2′:6′,2″-terpyridine ( tpy ) and its derivatives are important chelating ligands in coordination and supramolecular chemistry, yielding complexes with excellent electronic, optical and electrochemical properties [ 13 , 14 , 15 , 16 , 17 , 18 , 19 , 20 ]. Their coordination complexes, based on the cheap biocompatible and bioavailable Zn(II) metal center, were successfully used for obtaining polarized emissions [ 21 ] and emissive materials for optoelectronics and luminescence-based technologies [ 22 , 23 ], sensing and detection [ 24 , 25 , 26 , 27 , 28 , 29 , 30 , 31 , 32 , 33 ], DNA binding and/or cleavage agents [ 34 , 35 , 36 , 37 ] and bioimaging [ 38 , 39 , 40 ].…”

“…luminescence-based technologies [22,23], sensing and detection [24][25][26][27][28][29][30][31][32][33], DNA binding and/or cleavage agents [34][35][36][37] and bioimaging [38][39][40].…”

Role of the Environment Polarity on the Photophysical Properties of Mesogenic Hetero-Polymetallic Complex

“…2,2':6',2"-terpyridine (tpy) and its derivatives are important chelating ligands in coordination and supramolecular chemistry yielding complexes with excellent electronic, optical and electrochemical properties [13][14][15][16][17][18][19][20]. Their coordination complexes based on the cheap biocompatible and bioavailable Zn(II) metal center were successfully used for obtaining polarized emission [21] and emissive materials for optoelectronics and luminescence-based technologies [22,23], sensing and detection [24][25][26][27][28][29][30][31][32][33], DNA binding and/or cleavage agents [34][35][36][37], bioimaging [38][39][40].…”