Type-II heterojunction photocathode for CO<sub>2</sub> reduction and light-assisted metal–CO<sub>2</sub> batteries

Zhu, Yanbin; Wei, Yan; Li, Peize; Liu, Shujie; Zhang, Jiandong; Tian, Liyuan; Gao, Pengkun; Zhang, Yali; Li, Jie; Wang, Deyu; Shen, Yan; Wang, Mingkui

doi:10.1039/d3ta07450a

J. Mater. Chem. A

2024

DOI: 10.1039/d3ta07450a

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Type-II heterojunction photocathode for CO₂ reduction and light-assisted metal–CO₂ batteries

Yanbin Zhu,

Yan Wei,

Peize Li

et al.

Abstract: Light-assisted metal-CO2 batteries have attracted extensive attention. It is highly desirable to develop a photocathodic catalyst to simultaneously facilitate the activation and transformation of CO2 and maintain long-term operational stability....

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External Field‐Assisted Metal–Air Batteries: Mechanisms, Progress, and Prospects

Cao,

Liu,

et al. 2024

SusMat

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Metal–air batteries are an appealing option for energy storage, boasting a high energy density and environmental sustainability. Researchers focus on the catalyst design to solve the problem of sluggish cathode reaction kinetic. However, in some cases, where thermodynamic regulation is required, the role of catalysts is limited. Based on catalysts changing reaction kinetics, external fields can change the thermodynamic parameters of the reaction, further reduce overpotential, and accelerate the reaction rate. By selecting appropriate external fields and adjusting controllable variables, greater flexibility and potential are provided for reaction control. This paper reviews the basic principles by which several external fields influence metal–air batteries. Additionally, some design strategies of photoelectrode materials, the similarities and differences of different magnetic field effects, and some research progress of the ultrasonic field, stress field, and microwave field are systematically summarized. Multifield coupling can also interact and produce additive effects. Furthermore, introducing external fields will also bring about the problem of aggravated side reactions. This paper proposes some research methods to explore the specific reaction mechanism of external field assistance in more depth. The primary objective is to furnish theoretical direction for enhancing the performance of external field‐supported metal–air batteries, thereby advancing their development.

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External Field‐Assisted Metal–Air Batteries: Mechanisms, Progress, and Prospects

Cao,

Liu,

et al. 2024

SusMat

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show abstract

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Type-II heterojunction photocathode for CO₂ reduction and light-assisted metal–CO₂ batteries

Abstract: Light-assisted metal-CO2 batteries have attracted extensive attention. It is highly desirable to develop a photocathodic catalyst to simultaneously facilitate the activation and transformation of CO2 and maintain long-term operational stability....

Cited by 1 publication

References 45 publications

External Field‐Assisted Metal–Air Batteries: Mechanisms, Progress, and Prospects

External Field‐Assisted Metal–Air Batteries: Mechanisms, Progress, and Prospects

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Type-II heterojunction photocathode for CO2 reduction and light-assisted metal–CO2 batteries

Abstract: Light-assisted metal-CO2 batteries have attracted extensive attention. It is highly desirable to develop a photocathodic catalyst to simultaneously facilitate the activation and transformation of CO2 and maintain long-term operational stability....

Cited by 1 publication

References 45 publications

External Field‐Assisted Metal–Air Batteries: Mechanisms, Progress, and Prospects

External Field‐Assisted Metal–Air Batteries: Mechanisms, Progress, and Prospects

Contact Info

Product

Resources

About

Type-II heterojunction photocathode for CO₂ reduction and light-assisted metal–CO₂ batteries