1971
DOI: 10.1002/food.19710150609
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Über einige Eigentümlichkeiten in der Kinetik zu Beginn der Autoxydation von Estern ungesättigter Fettsäuren. 3. Mitt. Inhibierte Autoxydation

Abstract: Durch Untersuchungen über die Peroxidanhäufung in inhibierten Modell‐Lipidsystemen Methyloleat/α‐Naphthol und Methyllinoleat/α‐Naphthol wurde festgestellt, daß die Hydroperoxidkonzentration, bei der ein System die Induktionsperiode [ROOH]krit abschließt, eine charakteristische Größe ist, die von der Art des Lipidsystems und der Temperatur abhängt. Die Temperaturabhängigkeit der [ROOH]krit in ARRHENIUSkoordinaten wurde zur Bestimmung der Aktivierungsenergie der Umsetzung des Peroxidradikals des Methyllinoleats … Show more

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Cited by 21 publications
(4 citation statements)
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“…In this other experiment, the fish were caught in a different season and so the percentage of fat in muscle was lower, and also the initial concentrations of primary oxidation products (hydroperoxides) were higher. The initial concentration of primary autoxidation products (hydroperoxides) in lipids can substantially reduce the efficiency of the antioxidant added to the system being stabilized (Yanishlieva, 1973). These kinds of products are chain initiators, and their presence in the lipid system accelerates the process and reduces the time for inhibitor consumption (Yanishlieva, 1973).…”
Section: Lipid Oxidationmentioning
confidence: 99%
See 1 more Smart Citation
“…In this other experiment, the fish were caught in a different season and so the percentage of fat in muscle was lower, and also the initial concentrations of primary oxidation products (hydroperoxides) were higher. The initial concentration of primary autoxidation products (hydroperoxides) in lipids can substantially reduce the efficiency of the antioxidant added to the system being stabilized (Yanishlieva, 1973). These kinds of products are chain initiators, and their presence in the lipid system accelerates the process and reduces the time for inhibitor consumption (Yanishlieva, 1973).…”
Section: Lipid Oxidationmentioning
confidence: 99%
“…The initial concentration of primary autoxidation products (hydroperoxides) in lipids can substantially reduce the efficiency of the antioxidant added to the system being stabilized (Yanishlieva, 1973). These kinds of products are chain initiators, and their presence in the lipid system accelerates the process and reduces the time for inhibitor consumption (Yanishlieva, 1973). Antioxidants should therefore be added to foodstuffs as early as possible to achieve maximum protection against oxidation.…”
Section: Lipid Oxidationmentioning
confidence: 99%
“…The effectiveness of the added inhibitor is estimated on the basis of the induction period (IP), usually determined (in time units) by the method of applying the tangents to the two parts of the kinetic curves of oxidation products (in most cases peroxides) accumulation [19,20]. Alternatively, the time to reach a definite peroxide concentration is used [21].…”
Section: Introductionmentioning
confidence: 99%
“…IP, the time in which the concentration of the antioxidants (AH) is fully consumed, was determined as a cross point for the tangents to the two parts of the kinetic curves of lipid autoxidation [4,9,35,36]. IP A -stands for IP in the presence of AH and IP C -for the control lipid sample without AH.…”
Section: Induction Period (Ip)mentioning
confidence: 99%