With the increasing concerns over global warming and the growing demands for electricity, many researchers have considered renewable and sustainable resources for electricity/power generation. [1] Photovoltaics, thermoelectric, and electromagnetic induction are among the well-established technologies for electricity generation. [2] Mechanical energy is one of the most abundant and available resources that can be harvested to generate electricity. For example, mechanical energy is available in the form of human body motion and mechanical vibration. [3][4][5][6] Piezoelectric and triboelectric nanogenerators have both been used for mechanical energy harvesting. In triboelectric nanogenerators, electrical energy originates mainly from friction or temporary contact of two different layers. However, a wide range of deformation modes like bending, stretching, and vibration can generate electricity using piezoelectric nanogenerators (PNGs). The working mechanisms of PNGs are typically easier than triboelectric nanogenerators. [7] In addition, improving electrical output and reproducibility of triboelectric nanogenerators are still challenges. [8] The use of ferroelectric materials is a promising choice for energy harvesting. Ferroelectric materials show both piezoelectric (generation of electrical power from mechanical oscillation) and pyroelectric (generation of electricity from temperature fluctuation) properties. [9,10] Piezoelectric property offers conversion of mechanical energy to electricity. By applying mechanical stress, dipole momentum forms, leading to spontaneous polarization. Consequently, the electric current flows through the piezoelectric materials as a result of charge accumulation. [11] A wide range of piezoelectric materials is used as PNGs. Piezoelectric materials can be categorized into ceramics, polymers, and piezoelectret polymers. Materials with perovskite or wurtzite nanostructures show piezoelectric properties because their crystals are noncentral symmetry. Ceramics with perovskite