Ultrasound-assisted deep eutectic solvent microextraction procedure for traces Ponceau 4R in water and cosmetic samples

Shah, Syed Nasrullah; Uzcan, Furkan; Soylak, Mustafa

doi:10.1007/s13762-021-03154-z

Cited by 23 publications

(2 citation statements)

References 44 publications

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“…Pollution created by dye wastewater seriously harms human health and the natural ecological environment. Because, most of the dyestuffs, which are organic pollutants that cause environmental pollution, have a toxic effect even in very low concentrations in water [1][2][3][4]. Rhodamine 6G (Rh 6G) is one of the oldest and most wellknown Xanthan dye groups, and its derivatives are widely used in the textile, agriculture, cosmetics, food, pharmaceutical, paper, plastic, printing industries, and fluorescent labeling sectors.…”

Section: Introductionmentioning

confidence: 99%

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Özalp

Gümüş

Soylak

2023

J of Separation Science

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An NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) nanocomposite was synthesized for extraction and determination of Rhodamine (Rh) 6G from environmental and cosmetic samples. The deep eutectic solvent (DES) was prepared by mixing choline chloride and urea in a mole ratio of 1:2. NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) nanocomposite was synthesized using the impregnation method at a ratio of 60:40 (w/w). The optimum conditions were determined after NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) characterization was performed. The optimum conditions were determined as pH 8, adsorbent amount of 15 mg, total adsorption‐desorption time of 6 min, and enrichment factor of 20. The recovery values of the solid‐phase extraction method for water and cosmetic samples under optimum conditions were between 95% and 106%. NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) nanocomposite was an economically advantageous adsorbent because of its reusability of 15 times. All analyses were performed using the ultraviolet‐visible spectrophotometer. The linear range, limit of detection, and limit of quantification of the method were 100–1000, 9.80, and 32.68 μg/L, respectively. The obtained results showed that the synthesized nanocomposite is a suitable adsorbent for the determination of Rh 6G in water and cosmetic samples. The real sample applications were verified with the high‐performance liquid chromatography system.

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Section: Introductionmentioning

confidence: 99%

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Özalp

Gümüş

Soylak

2023

J of Separation Science

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“…LPME has some advantages such as economic extraction, rapid phase transportation, high capacity of extraction, and the facility of direct injection of samples into analytical instruments [9]. Numerous extraction methods including magnetic solid phase extraction [10,11], solid phase microextraction [12,13], hollow fber liquid phase microextraction [14,15], single drop microextraction [16], dispersive liquid-liquid microextraction [17], ultrasound-assisted LPME [18], and liquid-liquid microextraction [19,20] had been reported for the extraction and determination of synthetic dyes. In recent years, there has been an increasing focus on the utilization of deep eutectic solvents (DESs) as a novel green solvent.…”

Section: Introductionmentioning

confidence: 99%

Simultaneous Preconcentration of Fast Green FCF and Rhodamine B Using Deep Eutectic Solvent and Determination via High-Performance Thin Layer Chromatography

Karami,

Shokrollahi

2023

Journal of Analytical Methods in Chemistry

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The aim of the current investigation is the development of a green, quick, easy, and accurate method for simultaneous preconcentration of fast green FCF (FG) and rhodamine B (Rh B) using a deep eutectic solvent (DES). Then, the high-performance thin layer chromatography (HPTLC) technique was used for the determination of analytes. Decanoic acid and tetrabutylammonium bromide were chosen as the components of DES. HPTLC analysis was performed on an aluminum plate silica gel 60 F254. Methanol-ammonia and ethyl acetate were selected as the mobile phase. Scanning of the plates was accomplished by scanner 3. Effective parameters on the preconcentration process such as concentration of salt, volume of DES, stirrer time, and pH were investigated via central composite design (CCD). Data validation demonstrated good repeatability. The limit of detection for FG and Rh B was obtained as 0.08 and 0.01 µg·mL−1, respectively. The enrichment factor for FG and Rh B was achieved as 7.43 and 10.77, respectively. The linear ranges for FG and Rh B were acquired as 0.10–1.20 and 0.05–1.20 µg·mL−1, respectively. The preconcentration factor for both analytes was 21.66. Finally, the proposed method was successfully used for the quantitation of FG and Rh B in pastille and lipstick.

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Natural Material Shungite as Solid-Phase Extraction Sorbent for the Extraction of Red Synthetic Dye Ponceau 4R from Tap Water, Wine, and Juice

et al. 2021

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Ultrasound-assisted deep eutectic solvent microextraction procedure for traces Ponceau 4R in water and cosmetic samples

Cited by 23 publications

References 44 publications

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Simultaneous Preconcentration of Fast Green FCF and Rhodamine B Using Deep Eutectic Solvent and Determination via High-Performance Thin Layer Chromatography

Natural Material Shungite as Solid-Phase Extraction Sorbent for the Extraction of Red Synthetic Dye Ponceau 4R from Tap Water, Wine, and Juice

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