Understanding of nitrogen fixation electro catalyzed by molybdenum–iron carbide through the experiment and theory

Development of Electrocatalysts for Efficient Nitrogen Reduction Reaction under Ambient Condition

“…Therefore, a FE of 27% and a NH 3 yield rate of 72.5 µmol h −1 g −1 were achieved on Mo 3 Fe 3 C, outperformed most Mo 2 C‐based electrocatalysts. [ 76 ]…”

Progress in Mo/W-based electrocatalysts for nitrogen reduction to ammonia under ambient conditions

“…Since 2016, a lot of progress has been made regarding increasing the yield of NH 3 during the e-NRR process at ambient conditions. 44 Among all the reported electrocatalysts, immense efforts have been focused on the development of Mobased materials for the e-NRR, [45][46][47][48][49][50] especially MoS 2 -based catalysts, due to their high activity, stability, and suitable electronic structure. 51,52 As shown in Table 1, different studies of MoS 2 -based materials as e-NRR catalysts have been reported, with varying focuses on crystal phase types, morphologies, doping, and semiconductor hybrid.…”

Recent Advances in the Application of Structural‐Phase Engineering Strategies in Electrochemical Nitrogen Reduction Reaction

“…−1 at −0.05 V versus RHE. [ 21 ] This shows that in the development of NRR electrocatalysts, researchers have constructed different electrocatalyst materials based on the characteristics of NRR. Therefore, it is necessary to concisely analyze and comment on the recently reported electrocatalysts.…”

“…Therefore, it is necessary to concisely analyze and comment on the recently reported electrocatalysts. Here, we summarize the principles and related research on the construction of NRR electrocatalyst based on nano‐to‐atomic structure phase engineering strategy using strain engineering (Au@SnO 2 ), [ 22 ] defect engineering (VO‐Bi 4 O 5 I 2 ‐OH), [ 20 ] interface engineering (TiO 2 /Ti 3 C 2 T x ), [ 23 ] atomic arrangement engineering (Mo 3 Fe 3 C), [ 21 ] and single atom, to promote this uprising research field moving toward further development. Figure is a schematic diagram of a design strategy based on phase structure engineering.…”