2023
DOI: 10.1039/d3dt02087h
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Unexpected alkyl isomerization at the silicon ligand of an unsaturated Rh complex: combined experiment and theory

Niroshani S. Abeynayake,
Nghia Le,
Gabriela Sanchez-Lecuona
et al.

Abstract: The formation of dimer [ClRh(κ3(P,Si,Si)PhP(o-C6H4CH2SiiPr2)(o-C6H4CH2SiiPrnPr)]2 (Rh-3) with an n-propyl group on one of the silicon atoms as a minor product was affected from the reaction of [RhCl(COD)]2 and proligand PhP(o-C6H4CH2SiHiPr2)2,...

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