2024
DOI: 10.1002/ange.202420257
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Unexpected Magnetic Moments in Manganese‐Doped (CdSe)13 Nanoclusters: Role of Ligands

Guo‐Lun Huang,
Ko.‐Yu Ting,
Nagaraju Narayanam
et al.

Abstract: This study explores the enhancement in magnetic and photoluminescence properties of Mn2+‐doped (CdSe)13 nanoclusters, significantly influenced by the introduction of paramagnetic centers through doping, facilitated by optimized precursor chemistry and precisely controlled surface ligand interactions. Using a cost‐effective and scalable synthesis approach with elemental Se and NaBH4 (Se‐NaBH4) in n‐octylamine, we tailored bonding configurations (Cd‐O, Cd‐N, and Cd‐Se) on the surface of nanoclusters, as confirme… Show more

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