2024
DOI: 10.1002/ange.202416441
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Unlocking Oxetane Potential: Modular Synthetic Platform for the Concise Synthesis of Acyclic Oligo‐Isoprenoids and Terpenoids

Krisztián Albitz,
Sára Tóth,
Dániel Csókás
et al.

Abstract: Terpenes occupy a unique place among the secondary metabolites due to their broad utility and extraordinary structural diversity. Their synthesis via polyene cyclization, either biomimetic or enzymatic, represents the cutting edge of modern synthetic chemistry. However, these endeavors have been inherently tied to the availability of natural and non‐natural acyclic polyene starting materials. Herein, we report an oxetane‐based platform for the modular construction of oxygenated polyolefins with precise geometr… Show more

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