2024
DOI: 10.1002/ange.202410229
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Unlocking the Anion Effect on Steerable Production of 5‐Hydroxymethylfurfural

Jie Liang,
Chao Liu,
Jianchun Jiang
et al.

Abstract: Homogeneous metal salt catalysts play a pivotal role in industrial production of 5‐hydroxymethylfurfural (HMF). Herein, we first proposed the anion effect on steerable production of HMF using metal salts with different anions as catalyst in a biphasic system of tetrahydrofuran (THF)/NaCl aqueous solution (NaCl aq). Notably, the anions affected the catalytic activity of the metal salts, leading to an order of magnitude difference in the HMF yields, i.e., AlBr3 (74.0 mol %)>AlCl3 (60.8 mol %)>Al2(SO4)3 (35… Show more

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