Unravelling the 6sp ← 6s absorption spectra of Bi(iii) complexes
Charlene Harriswangler,
Fátima Lucio-Martínez,
Aurora Rodríguez-Rodríguez
et al.
Abstract:We report a spectroscopic and computational study that investigates the absorption spectra of Bi(III) complexes, which often show an absorption band in the UV region (~ 270-350 nm) due to...
Bismuth(III) alkanethiolates [Bi(SR)3] formed by reacting Bi2O3 with alkanethiols (RSH) undergo a UV-blue driven ligand-to-metal charge transfer photoreduction to disulfides and Bi colloids, which are then oxidised to Bi2O3 by...
Bismuth(III) alkanethiolates [Bi(SR)3] formed by reacting Bi2O3 with alkanethiols (RSH) undergo a UV-blue driven ligand-to-metal charge transfer photoreduction to disulfides and Bi colloids, which are then oxidised to Bi2O3 by...
A tetraazamacrocycle functionalised with thiosemicarbazone groups forms very stable complexes with alpha-emitting Bi and Pb radionuclides under mild reaction conditions.
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