2024
DOI: 10.1021/accountsmr.4c00166
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Unveiling Complex Structural Features of Thiolate-Protected Gold Nanoclusters: From Internal Core to External “Staple” Motifs and Overall Charge States

Wen Wu Xu,
Endong Wang,
Xiao Cheng Zeng

Abstract: Metrics & MoreArticle Recommendations CONSPECTUS:The revelation of numerous thiolate-protected gold nanocluster (TP-AuNCs) structures, achieved through a blend of theoretical predictions and experimental detection/validation, presents a vast amount of data for understanding the structural evolution of these nanoclusters. Typically, these clusters featured an internal gold core surrounded by external "staple" motifs SR[Au-(SR)] x (x = 0, 1, 2, 3, ...) at various charge states. In this Account, we outline our Gr… Show more

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