Uranyl complex with phenolate–sulphonate and diphenyldiazenecarbohydrazonate ligands

Solhnejad, Reza; Bahmanova, F. N.; Maharramov, Abel M.; Aliyeva, Rafiga A.; Chyragov, F. M.; Gurbanov, Atash V.; Mahmudova, Gunay S.; Mahmudov, Kamran T.; Kopylovich, Maximilian N.

doi:10.1016/j.inoche.2013.04.036

Cited by 4 publications

(1 citation statement)

References 31 publications

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“…The aromatic monosulfonates 4‐methylbenzenesulfonate and 2,4,6‐trimethylbenzenesulfonate behave as unidentate donors to uranyl ion,, but it was recently found that the former could also act as an O,O′ ‐bridging ligand . Various aromatic monosulfonates with additional carboxylate or hydroxyl coordinating groups also display unidentate sulfonate coordination (as part of a chelate ring), although O,O′ ‐bridging is also observed in some cases , , . Bridging of uranyl centres by disulfonate or mixed hydroxyl– or carboxylate–sulfonate ligands is propitious for the formation of uranyl–organic coordination polymers or frameworks (UOFs), a domain in which they are much less investigated than phosphonates .…”

Section: Introductionmentioning

confidence: 99%

Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

Thuéry

Harrowfield

2017

Eur J Inorg Chem

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International audienceUranyl nitrate was reacted with the sodium salt of either 1,5- or 2,7-naphthalenedisulfonate (1,5-ndsNa2 and 2,7-ndsNa2, respectively) under (solvo)-hydrothermal conditions, in the presence of additional coligands and/or metal cations, to give six new complexes which were characterized by their crystal structure determinations. [UO2(1,5-nds)(H2O)] (1) crystallizes as a three-dimensional (3D) framework, with both sulfonate groups coordinated in the O,Oʹ-bridging mode. In the presence of the N-chelating species 2,2ʹ-bipyridine (bipy) or 1,10-phenanthroline (phen), the three complexes [(UO2)2(1,5-nds)(OH)2(bipy)2]H2O (2), [(UO2)2(1,5-nds)(OH)2(bipy)2]bipy (3) and [(UO2)2(1,5-nds)(OH)2(phen)2] (4) were obtained, in which doubly hydroxide-bridged uranyl dimers are assembled into one-dimensional (1D) chains by bis(unidentate) disulfonate ligands. The complex [Cu(bipy)2Cl][UO2(2,7-nds)(OH)]H2O (5) displays anionic, two-dimensional (2D) sheets in which unidentate/O,Oʹ-bridging disulfonate ligands link hydroxide-bridged uranyl dimers. In the additional presence of cucurbit[6]uril (CB6), the complex [(UO2)4Na4(2,7-nds)2(CB6)Cl4O2(H2O)10]5H2O (6) crystallizes as a 3D framework of intricate architecture, with bis(3-oxo) bridged uranyl tetranuclear moieties connected to CB6-bound sodium cations by doubly O,Oʹ-bridging disulfonates. Complexes 2 and 4 display intense and well-resolved uranyl emission in the solid state, while nearly complete quenching is observed in 3 and 5

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Section: Introductionmentioning

confidence: 99%

Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

Thuéry

Harrowfield

2017

Eur J Inorg Chem

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Non-covalent interactions in the synthesis of coordination compounds: Recent advances

Mahmudov

Kopylovich

Silva

et al. 2017

Coordination Chemistry Reviews

288

155

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Low-Turn-On-Voltage, High-Brightness, and Deep-Red Light-Emitting Electrochemical Cell Based on a New Blend of [Ru(bpy)₃]²⁺ and Zn–Diphenylcarbazone

et al. 2018

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Deep red light-emitting electrochemical cells were prepared based on a blend of [Ru(bpy) 3 ] 2+ , a cationic complex, and a neutral Zn(II)-complex based on diphenylcarbazone ligands, named Zn(DPCO). The crystal structure of the Zn(DPCO) 2 (bpy)] molecule revealed that the DPCO ligand has been deprotonated to form DPCO – and coordinated to the Zn center metal through the C=O and N=N moieties of DPCO. From the cyclic voltammetry results and controlled potential coulometry data of the diphenylcarbazide (DPC) ligand, it is possible to establish that DPC is oxidized in an irreversible process at +0.77 V, giving DPCO and later oxidized at a higher potential (+1.32 V) to produce diphenylcarbadiazone (DPCDO). A detailed assignment of UV–vis spectra futures to determine the origin of ground- and excited-state transitions was achieved by time-dependent density functional theory calculations, which showed good agreement with the experimental results. Using a simple device architecture, we obtained deep red electroluminescence (EL) with high brightness (740 cd m –2 ) and luminous efficiency of 0.39 cd/A at a low turn-on voltage of 2.5 V. The favorable configuration of the cell consists of only a blend of complexes of indium tin oxide as the anode electrode and molten alloy cathode (Ga/In) without any polymer as the transporting layer. The comparison between [Ru(bpy) 3 ] 2+ and [Ru(bpy) 3 ] 2+ /Zn(DPCO) demonstrates a red shift in the EL wavelength from 625 to 700 nm in the presence of Zn(DPCO), revealing the importance of using blends for future systems.

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Uranyl complex with phenolate–sulphonate and diphenyldiazenecarbohydrazonate ligands

Cited by 4 publications

References 31 publications

Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

Non-covalent interactions in the synthesis of coordination compounds: Recent advances

Low-Turn-On-Voltage, High-Brightness, and Deep-Red Light-Emitting Electrochemical Cell Based on a New Blend of [Ru(bpy)₃]²⁺ and Zn–Diphenylcarbazone

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Uranyl complex with phenolate–sulphonate and diphenyldiazenecarbohydrazonate ligands

Cited by 4 publications

References 31 publications

Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

Non-covalent interactions in the synthesis of coordination compounds: Recent advances

Low-Turn-On-Voltage, High-Brightness, and Deep-Red Light-Emitting Electrochemical Cell Based on a New Blend of [Ru(bpy)3]2+ and Zn–Diphenylcarbazone

Contact Info

Product

Resources

About

Low-Turn-On-Voltage, High-Brightness, and Deep-Red Light-Emitting Electrochemical Cell Based on a New Blend of [Ru(bpy)₃]²⁺ and Zn–Diphenylcarbazone