2020
DOI: 10.26434/chemrxiv.12805331.v1
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Utilizing Selective Chlorination to Synthesize New Triangulenium Dyes with Redshifted Absorption and Emission

Abstract: Access to functionalization of a new site in the triangulenium core structure has been achieved at an early stageby chlorination with N-chlorosuccinimide (NCS), giving rise to two new triangulenium dyes (<b>1</b> and <b>2</b>). By introducing the chlorine functionalities in the acridinium precursor, positions complementary to those previously accessed by electrophilic aromatic substitution of the dyes are functionalized. The chlorination is highly selective giving only one regioisomer f… Show more

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