DOI: 10.32657/10356/61066
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Vanadium-doped and mixed Si/Ge-based apatites : synthesis, crystal chemistry and ionic conductivity

Abstract: Apatite-type oxides taking the general formula [A I 4 ][A II 6 ][(BO 4) 6 ][X 2±y ], particularly those of the rare earth silicate and germanate systems, are among the more promising materials being considered as alternative solid oxide fuel cell electrolytes. Nonstoichiometric lanthanum silicate and germanate apatites display pure ionic conductivities exceeding those of yttria-stabilized zirconia at moderate temperatures (500-800 ºC). Indeed, it is the underlying complexity and flexibility of these substances… Show more

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