Org. Chem. Front.
 2024
DOI: 10.1039/d4qo00312h
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Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading

Fang-Fang Xu,
Zhong-Lei Ruan,
Pei-Qiang Huang

Abstract: Herein we report the catalytic deoxygenative reduction of sulfoxides to give sulfides in good to excellent yields. The method was enabled by the combination of Vaska’s complex with poly(methylhydrosiloxane) (PMHS)....

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