1952
DOI: 10.1021/ja01128a049
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Vinyl Polymerization with Radioactive Aliphatic Azobisnitrile Initiators1

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Cited by 85 publications
(16 citation statements)
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“…The initiator efficiency for any particular initiator may also vary for different monomers. Thus the value of f for AIBN in the polymerizations of methyl methacrylate, vinyl acetate, styrene, vinyl chloride, and acrylonitrile ranged from 0.6 to 1.0, increasing in that order [Arnett and Peterson, 1952]. This order is a consequence of the relative rates with which radicals add to the different monomers.…”
Section: -4g-2 Mechanism Of F < 1: Cage Effectcontrasting
confidence: 64%
“…The initiator efficiency for any particular initiator may also vary for different monomers. Thus the value of f for AIBN in the polymerizations of methyl methacrylate, vinyl acetate, styrene, vinyl chloride, and acrylonitrile ranged from 0.6 to 1.0, increasing in that order [Arnett and Peterson, 1952]. This order is a consequence of the relative rates with which radicals add to the different monomers.…”
Section: -4g-2 Mechanism Of F < 1: Cage Effectcontrasting
confidence: 64%
“…Although thought otherwise in the past (see, e.g., Ref. [25][26][27], the number of initiator end groups per polymer molecule was determined. † Probably the most compelling evidence for this is the experimental observation that the ratio of k td /k tc is (weakly) temperature dependent (21,24).…”
Section: Disproportionation Versus Combinationmentioning
confidence: 99%
“…A study of the stabilities and of the electrophoretic properties of monodispersed polystyrene lattices has been reported water interface, and found two generalizations could be made: (1) There was no dependence of electrophoretic mobility on soap coverage.…”
Section: Stability Of L a T E X Particles In A Polymerizing Emulsionmentioning
confidence: 99%