This work is devoted to the research of new asymmetry effects in symmetric protective structures with triple modal reservation. We analyzed the structures with different cross-sectional locations of the reference conductor: in the center (unshielded structure), around (shielded structure), at the top and bottom (multilayer printed circuit board), and in the form of side polygons (double-sided printed circuit board). First, a preliminary quasi-static simulation was performed in the range of parameters. It was revealed that in all structures, except for the shielded one (in the form of a cable), the deviations of the output voltage amplitude, bandwidth, and frequency of the first resonance were insignificant, whereas in the shielded structure there were significant deviations in the time and frequency responses. The attenuation of the output voltage in relation to the input for each structure was also estimated. In addition, we performed a parametric optimization of the structures under consideration using a heuristic search, which made it possible to improve their characteristics. Finally, the switching order between the conductors in these structures with the original and optimized parameter sets was investigated in detail. The optimal conductor switching order in the case of a component failure was determined, and the best (according to protective characteristics) parameter configuration for each structure was found.