“…This should allow the host to be doped with large amounts of dopant without the niobate structure changing significantly. 55 According to the La 2 O 3 -Nb 2 O 5 phase diagram, lanthanum niobate consists of four defined compounds: La 3 NbO 7 , LaNbO 4 , LaNb 3 O 9 , and La 2 Nb 12 O 33 . 56 La 3 NbO 7 , an orthorhombic perovskite, is employed as the electrolyte, 57 and so is LaNbO 4 , an orthoniobate with a monoclinic structure that adopts the tetragonal structure at higher temperatures.…”