“…All the data are positive and rise with the increasing temperature as the intermolecular distance increases. The structural formula plays an important role in deciding the values of thermal expansion [36]. The obtained results are further used to calculate thermal expansion coefficients and excess thermal expansion coefficients of the binary mixtures over the whole mole fraction range.…”
“…All the data are positive and rise with the increasing temperature as the intermolecular distance increases. The structural formula plays an important role in deciding the values of thermal expansion [36]. The obtained results are further used to calculate thermal expansion coefficients and excess thermal expansion coefficients of the binary mixtures over the whole mole fraction range.…”
“…The sign of ð@ 2 V 0 / =@T 2 Þ predicts [35,38] whether the particular solute when dissolved in a solvent will act as a structure maker or a structure breaker. The quantity ð@ 2 V 0 / =@T 2 Þ will be positive for structure making solutes, while for structure breaking solutes ð@ 2 V 0 / =@T 2 Þ will be negative.…”
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