Water-based chitosan/melamine polyphosphate multilayer nanocoating that extinguishes fire on polyester-cotton fabric

Leistner, Marcus; Abu-Odeh, Anas; Rohmer, Sarah C.; Grunlan, Jaime C.

doi:10.1016/j.carbpol.2015.05.005

Cited by 91 publications

(43 citation statements)

References 26 publications

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“…Recently, LbL has been used to assembly eco-friendly flame retardants on fabrics (Alongi, Carletto et al, 2013;Alongi, Carosio, Frache, & Malucelli, 2013;Carosio, Di Blasio, Alongi, & Malucelli, 2013;Yang, Cao, Wang, & Schiraldi, 2015). Through alternating deposition of oppositely charged polyelectrolytes, cotton fabrics, ramie fabrics and PET fabrics were coated in a control way (Carosio et al, 2011a;Carosio, Alongi, & Malucelli, 2012;Chang, Slopek, Condon, & Grunlan, 2014;Leistner, Abu-Odeh, Rohmer, & Grunlan, 2015;Li, Mannen et al, 2011;Pan et al, 2015;Zhang, Yan, Peng et al, 2013;. Despite the enhanced flame retardancy, the washing fastness capacity of the add-on flame retardants via LbL assembly urgently requires improvement.…”

Section: Introductionmentioning

confidence: 98%

Flame retardation of cellulose-rich fabrics via a simplified layer-by-layer assembly

Yang

Wang

Deng

et al. 2016

Carbohydrate Polymers

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Section: Introductionmentioning

confidence: 98%

Flame retardation of cellulose-rich fabrics via a simplified layer-by-layer assembly

Yang

Wang

Deng

et al. 2016

Carbohydrate Polymers

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“…The layer-by-layer coating technique was also exploited to deposit a highly effective flame retardant (melamine polyphosphate) from water onto polyester-cotton fabrics [104]. The reaction between soluble melamine and sodium hexametaphosphate gave rise to a water-insoluble flame retardant during the coating procedure: the obtained nanocoating was able to provide self-extinction properties to polyester-cotton fabrics with only 12% relative coating weight.…”

Section: Intumescent Lbl Coatingsmentioning

confidence: 99%

Surface-Engineered Fire Protective Coatings for Fabrics through Sol-Gel and Layer-by-Layer Methods: An Overview

Malucelli

2016

Coatings

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Fabric flammability is a surface-confined phenomenon: in fact, the fabric surface represents the most critical region, through which the mass and heat transfers, responsible for fueling the flame, are controlled and exchanged with the surroundings. More specifically, the heat the fabric surface is exposed to is transferred to the bulk, from which volatile products of thermal degradation diffuse toward the surface and the gas phase, hence feeding the flame. As a consequence, the chemical and physical characteristics of the fabric surface considerably affect the ignition and combustion processes, as the surface influences the flux of combustible volatile products toward the gas phase. In this context, it is possible to significantly modify (and improve) the fire performance of textile materials by "simply" tailoring their surface: currently, one of the most effective approaches exploits the deposition of tailored coatings able to slow down the heat and mass transfer phenomena occurring during the fire stages. This paper reviews the current state of the art related to the design of inorganic, hybrid, or organic flame-retardant coatings suitable for the fire protection of different fabric substrates (particularly referring to cotton, polyester, and their blends). More specifically, the use of sol-gel and layer-by-layer (LbL) methods is thoroughly discussed; then, some recent examples of flame retardant coatings are presented, showing their potential advances and their current limitations.

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“…Very recently, the LbL technique has also been exploited for depositing intumescent-like coatings but having a "green" composition and derived from renewable sources. In particular, chitosan/phytic acid bilayers [38], chitosan/DNA-based assemblies [39], starch/polyphosphoric acid [40], chitin derivatives [41], chitosan/melamine polyphosphate [42] and phosphorylated poly(vinyl alcohol)/chitosan [43] have been successfully employed for conferring flame retardant features to cotton.…”

Section: Applications Of Layer-by-layer Assemblies To Fabricsmentioning

confidence: 99%

Layer-by-Layer nanostructured assemblies for the fire protection of fabrics

Malucelli

2016

Materials Letters

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Water-based chitosan/melamine polyphosphate multilayer nanocoating that extinguishes fire on polyester-cotton fabric

Cited by 91 publications

References 26 publications

Flame retardation of cellulose-rich fabrics via a simplified layer-by-layer assembly

Flame retardation of cellulose-rich fabrics via a simplified layer-by-layer assembly

Surface-Engineered Fire Protective Coatings for Fabrics through Sol-Gel and Layer-by-Layer Methods: An Overview

Layer-by-Layer nanostructured assemblies for the fire protection of fabrics

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