What is Electrochemistry ?

Parsons, Rion

doi:10.1007/978-1-4684-5098-9_3

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“…In principle, two limiting cases can be considered for the adsorption process-activation control and transport control (20,22,23). These cases predict that the temporal dependence of the surface coverage should be governed by and in which ⌫ t is the coverage at time t , ⌫ s is the saturation coverage, ⌫ e is the equilibrium coverage at a bulk concentration C*, k´ is the rate constant, K is a constant, and D is the diffusion coefficient (20 -24).…”

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confidence: 99%

Peer Reviewed: Redox and Photoactive Dendrimers in Solution and on Surfaces

Abruña¹

2004

Anal. Chem.

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Because of the broad range of potential applications, interest in the preparation and characterization of redox and photoactive supramolecular structures, particularly dendrimers, is widespread. These applications include sensors, electrochromic and electroluminescent display devices, light harvesting, redox mediators, molecular electronics, and MRI materials. Dendrimers are highly branched globular molecules that consist of a core, selfreplicating branching units, and peripheral surface groups ( Figure 1); given their relatively high molecular weight, they can be considered "monodisperse polymers" (1-4). Dendrimers can be functionalized with reactive groups at the core, at the periphery, or throughout the entire structure and are ideal platforms for modification with redox and photoactive groups (5-8). We have synthesized and characterized dendrimers that are decorated on the periphery with redox and photoactive centers based on transition metal complexes and explored their electro-and photochemical properties in solution and on surfaces.

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Section: +mentioning

confidence: 99%

Peer Reviewed: Redox and Photoactive Dendrimers in Solution and on Surfaces

Abruña¹

2004

Anal. Chem.

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What is Electrochemistry ?

Cited by 1 publication

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Peer Reviewed: Redox and Photoactive Dendrimers in Solution and on Surfaces

Peer Reviewed: Redox and Photoactive Dendrimers in Solution and on Surfaces

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