A micro-ring resonator structure was fabricated via the two-photon polymerization technique directly on a single-mode fiber tip and tested for refractive index sensing application. The micro-ring structure was used to excite whispering-gallery modes, and observations of the changes in the resonance spectrum introduced by changes in the refractive index of the environment served as the sensing principle. The proposed structure has the advantages of a very simple design, allowing for measurements in reflection mode, relatively easy and fast fabrication and integration with a single tip of a standard single-mode fiber, which allowed for quick and convenient measurements in the optical setup. The performance of the structure was characterized, and the resonant spectrum giving high potential for refractive index sensing was measured. Future perspectives of the research are addressed.