Wronskian method and the Schrödinger eigenvalue march

Abstract

We compare the Wronskian method (WM) and the Schrödinger eigenvalue march or canonical function method (SEM-CFM) for the calculation of the energies and eigenfunctions of the Schrödinger equation. The Wronskians between linearly independent solutions of the Schrödinger equation provide a rigorous basis for some of the assumptions of the SEM-CFM, like, for example, the concept of "saturation".We compare the performance of both approaches on a simple one-dimensional model and suggest that taking into account the asymptotic behaviour of the wavefunction (as is already done in the WM) may make the SEM-CFM more efficient from a numerical point of view.