Abstract:Crystal structure of Cr(II) phthalocyaninate (CrPc) was determined by means of single-crystal X-ray diffraction. It was shown that after vacuum sublimation CrPc crystallized as a β-polymorph, which was isostructural to β-polymorphs of other metal phthalocyanines. When deposited onto glass substrate by organic molecular beam deposition, CrPc formed thin films with strong preferred orientation, consisting of α-polymorph. It was shown that both β-CrPc powder and α-CrPc films were unstable in air and transformed t… Show more
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