Abstract:The new tert butoxide yttrium complex [C 6 H 4 1,2 {NC(Bu t )N(2,6 Me 2 C 6 H 3 )} 2 ]YOBu t (DME) containing the dianionic ansa linked bis(amidinate) ligand with the rigid o phenylene linker was synthesized by the metathesis of the chloride complex [C 6 H 4 1,2 {NC(Bu t )N(2,6 Me 2 C 6 H 3 )} 2 ]Y(THF)( 2 Cl) 2 Li(THF) 2 with potassium tert butoxide and structurally charac terized. The synthesized yttrium bis(amidinate) tert butoxide complex exhibits a moderate catalytic activity in the polymerization of rac… Show more
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