Zeolite-Templated Carbon as the Cathode for a High Energy Density Dual-Ion Battery

Dubey, Romain; Nussli, Jasmin; Piveteau, Laura; Kravchyk, Kostiantyn V.; Rossell, Marta D.; Campanini, Marco; Erni, Rolf; Kovalenko, Maksym V.; Stadie, Nicholas P.

doi:10.1021/acsami.9b03886

Cited by 35 publications

(26 citation statements)

References 73 publications

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“…Recently, Stadie et al extend the applications of zeolite-templated nanocarbon materials to the aluminum battery (AB), [82] the magnesium-ion battery, [273] and dual-ion batteries. [80] Aluminum Battery: Practical rechargeable batteries with Al anodes were reported until recently because of the formation of solid-electrolyte interphase (SEI) and lagged development of suitable electrolytes. [274,275] Graphite-based materials are employed as cathode with ionic liquid of [EMIm]Cl as electrolyte, which can mitigate and avoid the interphase formation.…”

Section: The Aluminum Battery the Magnesium-ion Battery And Dual-iomentioning

confidence: 99%

“…extend the applications of zeolite‐templated nanocarbon materials to the aluminum battery (AB), [ 82 ] the magnesium‐ion battery, [ 273 ] and dual‐ion batteries. [ 80 ]…”

Section: Energy Applications Of Nanocarbon Materials Templated By Zeomentioning

confidence: 99%

“…In the example of dual‐ion battery reported by Stadie et al., bis(fluorosulfonyl)imide (FSI − ) was selected as an optimal anion due to its reported successful utilization in DIBs. [ 80 ] Potassium was selected as a suitable cation due to its high natural abundance and excellent electroplating/stripping properties. The most well‐understood FAU zeolite‐templated porous carbon was employed as cathode due to its high specific surface area, ordered porous structure, and applicable size of pores.…”

Section: Energy Applications Of Nanocarbon Materials Templated By Zeomentioning

confidence: 99%

“…storage materials and electrocatalysts: more specifically, high specific surface area is beneficial for gas adsorption [73] and improvement of double layer capacitance; [55,[74][75][76][77][78][79] the zeolite-templated carbon frameworks with high conductivity are also suitable candidates as electrode materials [55,73,74,77,[79][80][81][82][83][84][85][86][87][88][89][90] and promising scaffolds for electrocatalysts; [81,[91][92][93][94][95][96] hierarchically ordered porosity can enhance mass transfer without pore blockage, [78,91,[97][98][99] which has already been employed as the host of active materials in electrode; [83,85,100] plus ultrafine nanostructures anchored on zeolite-templated nanocarbons, enhanced electrocatalytic performance can be implemented by synergic effect of nanocarbons and metal nanostructures. [81,91] The definition of nanocarbons was proposed by Inagaki et al, [101,102] which contemplates not only the control of size but also the control of struct...…”

Section: Introductionmentioning

confidence: 99%

“…It is becoming urgent topic for scientists to explore environmentally benign energy storage devices [ 66–70 ] and look for renewable alternatives of traditional fuels. [ 71,72 ] Zeolite‐templated nanocarbons (ZTNCs), possessing remarkable mechanical, optical, electrical, and catalytic properties, endow them enormous potential as energy storage materials and electrocatalysts: more specifically, high specific surface area is beneficial for gas adsorption [ 73 ] and improvement of double layer capacitance; [ 55,74–79 ] the zeolite‐templated carbon frameworks with high conductivity are also suitable candidates as electrode materials [ 55,73,74,77,79–90 ] and promising scaffolds for electrocatalysts; [ 81,91–96 ] hierarchically ordered porosity can enhance mass transfer without pore blockage, [ 78,91,97–99 ] which has already been employed as the host of active materials in electrode; [ 83,85,100 ] plus ultrafine nanostructures anchored on zeolite‐templated nanocarbons, enhanced electrocatalytic performance can be implemented by synergic effect of nanocarbons and metal nanostructures. [ 81,91 ]…”

Section: Introductionmentioning

confidence: 99%

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Revival of Zeolite‐Templated Nanocarbon Materials: Recent Advances in Energy Storage and Conversion

et al. 2020

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Nanocarbon materials represent one of the hottest topics in physics, chemistry, and materials science. Preparation of nanocarbon materials by zeolite templates has been developing for more than 20 years. In recent years, novel structures and properties of zeolite-templated nanocarbons have been evolving and new applications are emerging in the realm of energy storage and conversion. Here, recent progress of zeolite-templated nanocarbons in advanced synthetic techniques, emerging properties, and novel applications is summarized: i) thanks to the diversity of zeolites, the structures of the corresponding nanocarbons are multitudinous; ii) by various synthetic techniques, novel properties of zeolite-templated nanocarbons can be achieved, such as hierarchical porosity, heteroatom doping, and nanoparticle loading capacity; iii) the applications of zeolite-templated nanocarbons are also evolving from traditional gas/vapor adsorption to advanced energy storage techniques including Li-ion batteries, Li-S batteries, fuel cells, metal-O 2 batteries, etc. Finally, a perspective is provided to forecast the future development of zeolite-templated nanocarbon materials.

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Section: The Aluminum Battery the Magnesium-ion Battery And Dual-iomentioning

confidence: 99%

“…extend the applications of zeolite‐templated nanocarbon materials to the aluminum battery (AB), [ 82 ] the magnesium‐ion battery, [ 273 ] and dual‐ion batteries. [ 80 ]…”

Section: Energy Applications Of Nanocarbon Materials Templated By Zeomentioning

confidence: 99%

Section: Energy Applications Of Nanocarbon Materials Templated By Zeomentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Revival of Zeolite‐Templated Nanocarbon Materials: Recent Advances in Energy Storage and Conversion

et al. 2020

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A Review of Emerging Dual‐Ion Batteries: Fundamentals and Recent Advances

Zhang

Wang

Zhang

et al. 2021

Adv Funct Materials

158

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Dual‐ion batteries (DIBs), based on the working mechanism involving the storage of cations and anions separately in the anode and cathode during the charging/discharging process, are of great interest beyond lithium‐ion batteries (LIBs) in high‐efficiency energy storage due to the merits of high working voltage, material availability, as well as low cost and excellent safety. Despite the progress achieved, the practical applications of DIBs are still hindered by negative issues, such as limited capacity and cyclic stability, which triggers the development of suitable electrode materials with highly reversible capacities, and corresponding electrolytes with high oxidative stability as well as sufficient reaction kinetics of active ions. Herein, in this article, a systematic and comprehensive review of fundamentals and recent advances in current DIBs with subcategories of cathode materials, anode materials, and electrolytes are presented. In particular, their energy storage mechanisms, as well as their respective features, are dissected. Furthermore, some strategies and perspectives are proposed for facilitating the further development of DIBs in the future.

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Sustainable Dual‐Ion Batteries beyond Li

Zhao,

Alshareef

2023

Advanced Materials

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The limitations of resources used in current Li‐ion batteries render them unsuitable for grid energy storage systems, prompting the search for low‐cost and resource‐abundant alternatives. “Beyond‐Li cation” batteries have emerged as promising contenders; however, they confront noteworthy challenges due to the scarcity of suitable host materials for these cations. In contrast, anions, the other crucial component in electrolytes, demonstrate reversible intercalation capacity in specific materials like graphite. The convergence of anion and cation storage has given rise to a new battery technology known as dual‐ion batteries (DIBs). This comprehensive review presents the current status, advancements, and future prospects of sustainable DIBs beyond Li. Notably, most DIBs exhibit similar cathode reaction mechanisms involving anion intercalation, while the distinguishing factor lies in the cation types functioning at the anode. Accordingly, this review is organized into sections by various cation types, including Na‐, K‐, Mg‐, Zn‐, Ca‐, Al‐, NH4+‐, and proton‐based DIBs. Moreover, a perspective on these novel DIBs is presented, along with proposed protocols for investigating DIBs and promising future research directions. We envision that this review will inspire fresh concepts, ideas, and research directions, while raising important questions to further tailor and understand sustainable DIBs, ultimately facilitating their practical realization.This article is protected by copyright. All rights reserved

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Zeolite-Templated Carbon as the Cathode for a High Energy Density Dual-Ion Battery

Cited by 35 publications

References 73 publications

Revival of Zeolite‐Templated Nanocarbon Materials: Recent Advances in Energy Storage and Conversion

Revival of Zeolite‐Templated Nanocarbon Materials: Recent Advances in Energy Storage and Conversion

A Review of Emerging Dual‐Ion Batteries: Fundamentals and Recent Advances

Sustainable Dual‐Ion Batteries beyond Li

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