Zinc(II) coordination polymer on the base of 3′-(1 H -tetrazol-5- yl )-[1,1′-biphenyl]-4-carboxylic acid: Synthesis, crystal structure and antimicrobial properties

Bahrin, Lucian Gabriel; Roșca, Irina; Clima, Lilia; Shova, Sergiu; Bejan, Dana; Nicolescu, Alina; Marangoci, Narcisa-Laura; Sardaru, Monica C.; Lozan, Vasile; Rotaru, Alexandru

doi:10.1016/j.inoche.2018.03.026

Cited by 7 publications

(3 citation statements)

References 33 publications

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“…Zn (II)-MOFs 42, which is based on 3′-(1H-tetrazol-5-yl)- [1,10 -biphenyl]−4-carboxylic acid, shown strong antifungal action [ 151 ]. In addition to Zn (II), Ni (II), and Cu (II)-MOFs, which are only reported to be effective against Candida albicans .…”

Section: Antifungal Activities Of Mofsmentioning

confidence: 99%

Recent advances and potential applications for metal-organic framework (MOFs) and MOFs-derived materials: Characterizations and antimicrobial activities

Hubab,

Al-Ghouti

2024

Biotechnology Reports

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Section: Antifungal Activities Of Mofsmentioning

confidence: 99%

Recent advances and potential applications for metal-organic framework (MOFs) and MOFs-derived materials: Characterizations and antimicrobial activities

Hubab,

Al-Ghouti

2024

Biotechnology Reports

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“…In the past few years, our interest in the field has led to several new Metal-Organic Frameworks, as well as a number of organic linkers that can be used in MOF design [24][25][26][27][28][29][30][31][32][33][34][35][36]. With the goal of obtaining novel MOFs with permanent porosity which have the potential to be used for gas storage, in this work we synthesized and characterized three new Metal-Organic Frameworks, obtained using Zn (II) and Cd (II) as metal sources and 2,4,6-tris(4carboxyphenyl)-1,3,5-trimethylbenzene (mesitylene tribenzoic acid-H 3 MTB) an organic linker which to this day, has only seen limited use in MOF design.…”

Section: Introductionmentioning

confidence: 99%

Mesitylene Tribenzoic Acid as a Linker for Novel Zn/Cd Metal-Organic Frameworks

Bejan¹,

Dascalu²,

Shova³

et al. 2022

Materials

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Three new Metal-Organic Frameworks, containing mesitylene tribenzoic acid as a linker and zinc (1) or cadmium as metals (2,3), were synthesized through solvothermal reactions, using DMF/ethanol/water as solvents, at temperatures of 80 °C (structures 1 and 3) and 120 °C (structure 2). Following single-crystal X-ray diffraction, it was found that 1 and 3 crystallize in the P21/c and C2/c space groups and form 2D networks, while 2 crystallizes in the Fdd2 space group, forming a 3D network. All three frameworks, upon heating, were found to be stable up to 350 °C. N2 sorption isotherms revealed that 1 displays a BET area of 906 m2/g. Moreover, the porosity of this framework is still present after five cycles of sorption/desorption, with a reduction of 14% of the BET area, down to 784 m2/g, after the fifth cycle. The CO2 loading capacity of 1 was found to be 2.9 mmol/g at 0 °C.

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“…Our continued interest in the field of azole derivatives [ 27 , 28 , 29 , 30 , 31 ], as well as MOF design [ 32 , 33 , 34 ], led to the synthesis and characterization of four new azole-based linkers with a mesitylene core.…”

Section: Introductionmentioning

confidence: 99%

Nitrogen-Based Linkers with a Mesitylene Core: Synthesis and Characterization

et al. 2021

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Mesitylene was used as a core in seven new tritopic nitrogen containing linkers. Three of the linkers, each containing three nitrile groups, were obtained through Suzuki, Sonogashira and Heck-type coupling reactions. Next, these were converted to tetrazol-5-yl moieties by the cycloaddition of sodium azide to the nitrile functionalities. The last linker, containing three 1,2,3-triazol-4-yl moieties, was synthesized by the Huisgen cycloaddition of phenyl azide to the corresponding alkyne. The latter was obtained via a Corey–Fuchs reaction sequence from the previously reported formyl derivative. As the proof of concept for their potential in MOF design, one of the nitriles was used to build an Ag-based network.

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Zinc(II) coordination polymer on the base of 3′-(1 H -tetrazol-5- yl )-[1,1′-biphenyl]-4-carboxylic acid: Synthesis, crystal structure and antimicrobial properties

Cited by 7 publications

References 33 publications

Recent advances and potential applications for metal-organic framework (MOFs) and MOFs-derived materials: Characterizations and antimicrobial activities

Recent advances and potential applications for metal-organic framework (MOFs) and MOFs-derived materials: Characterizations and antimicrobial activities

Mesitylene Tribenzoic Acid as a Linker for Novel Zn/Cd Metal-Organic Frameworks

Nitrogen-Based Linkers with a Mesitylene Core: Synthesis and Characterization

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