ZnS Nanocrystals as an Additive for Gamma-Irradiated Poly (Vinyl Chloride)

Silva, Roberta Cristina da; Silva, Lindomar Avelino da; Araújo, Patrícia Lopes Barros de; Araújo, Elmo S.; Santos, Renata Francisca da Silva; Aquino, Kátia Aparecida da Silva

doi:10.1590/1980-5373-mr-2016-0983

Cited by 13 publications

(2 citation statements)

References 35 publications

(33 reference statements)

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“…The enhancement in the FL intensity, upon loading with ZnS/Mn, may be attributed to the presence of intermolecular interactions between the PVC molecules and ZnS. Sliva et al [43] attributed the changes in the C-Cl stretching FTIR peaks of the PVC/ZnS composite to the interaction between the PVC chlorine atom and ZnS, which is confirmed by the PCA (principal component analysis) of the FTIR pure PVC and PVC/ZnS spectra. A similar enhancement was observed for a PVA/ZnS composite [44], and for PVP-coated ZnS [45].…”

Section: Fluorescence Analysismentioning

confidence: 75%

Impact of ZnS/Mn on the Structure, Optical, and Electric Properties of PVC Polymer

et al. 2023

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The most efficient way to create novel materials that may be used in a variety of optoelectronic applications is thought to be doped mixed polymers with appropriate fillers. Undoped and doped PVC polymers with ZnS/Mn formed at different temperatures were fabricated using the casting method. The Rietveld method was used to discover the structure and microstructure of Zn0.95Mn0.05S prepared at T = 300, 400, and 500 °C. The distribution and existence of the nanofiller over the PVC matrix were determined via XRD, FTIR, EDS, and SEM techniques. The effect of the preparation temperatures of the ZnS/Mn nanofiller on the absorption, transmittance, reflectance, refractive index, extinction coefficient, dielectric constant, AC conductivity, electrical modulus, and DC conductivity activation energy data of the PVC polymer was studied using the diffused reflectance technique. Doping PVC with ZnS/Mn (prepared at 300 °C) lowered the direct and indirect optical band gaps from 5.4 and 4.52 eV to minimum values of 4.55 and 3.63 eV. The fluorescence intensity of pure PVC is greatly enhanced upon loading with ZnS/Mn. The PVC exhibited two near UV peaks, one violet and one blue color, while, in addition, the doped polymers exhibited green and orange colors. The corresponding CIE diagram for all the samples was also determined.

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Section: Fluorescence Analysismentioning

confidence: 75%

Impact of ZnS/Mn on the Structure, Optical, and Electric Properties of PVC Polymer

et al. 2023

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“…Stabilizers like free radical scavengers (primary antioxidants) can prevent the main scission and cross-linking 13,21 . In addition, our most recent studies have shown the efficiency of using nanoparticles in the same amount of commercial additives as stabilizers for PMMA and Poly (vinyl chloride) (PVC) exposed to gamma radiation [22][23][24][25] .…”

Section: Commercial Additives For Polymer Matrixmentioning

confidence: 99%

Study of Commercial Additive Effects on the Poly(methyl methacrylate) Exposed to Gamma Irradiation by Viscosimetric Analysis

Aquino,

Oliveira,

Santos

et al. 2023

Mat. Res.

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Poly(methyl methacrylate) (PMMA) is a polymer with applications in the medical and aerospace industries that require resistance to gamma radiation. However, the effects caused by gamma radiation on PMMA properties may make its application in situations of exposure to gamma radiation unfeasible. In this study, the impact of commercial additives on the radiolytic stabilization of PMMA will be studied through viscosimetric assays. In a preliminary trial, additives with different mechanisms of action were tested, and the efficacy of two additives (Tinuvin 770 and Tinuvin 622) hindered amine stabilizers (HAS) types were registered. PMMA films with the additives at different concentrations were exposed to gamma radiation and studied through viscosimetric molar mass and G-value. The Tinuvin 622 at 0.3 wt% showed the best performance in the radiolytic stabilization of p PMMA films at the 20-50 kGy range. Antagonism was observed when Tinuvin 700 and Tinuvin 622 mixture was studied in different proportions. These results show the potential of commercial additives, initially produced for other purposes, in the radiolytic stabilization of PMMA.

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ZnS Nanoparticles‐decorated Composite Graphene Paper: A Novel Flexible Electrochemical Sensor for Detection of Dopamine

et al. 2021

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Dopamine (DA) is a significant catecholamine neurotransmitter in human metabolism, and DA is related to several critical illnesses. Accurate detection of DA is important to diagnose these diseases. Here, we demonstrated a flexible electrochemical sensor, ZnS nanoparticles decorated composite graphene paper electrode (CGPE), for the detection of DA. CGPE was prepared via mold‐casting method using ZnS/graphene oxide dispersion followed by thermal reduction treatment. The characterization of the flexible CGPE was investigated through various techniques. The electrochemical tests were carried out to study the electrocatalytic properties of CGPE against DA oxidation. Compared to graphene paper electrode (GPE), the oxidation of DA occurred at about 250 mV lower potential on CGPE, and peak current density increased about 2 times. Our sensor exhibited high sensitivity in linear range of 0.1–2300 μM of DA with a limit of detection (LOD) of 0.0042 μM. Furthermore, CGPE has selectively detected DA even in the medium containing AA and UA which are biologically active interfering molecules. Besides, the sensor showed many attractive properties such as high durability, stability, and reproducibility and it was successfully applied for the determination of DA in real samples for practical applications.

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ZnS Nanocrystals as an Additive for Gamma-Irradiated Poly (Vinyl Chloride)

Cited by 13 publications

References 35 publications

Impact of ZnS/Mn on the Structure, Optical, and Electric Properties of PVC Polymer

Impact of ZnS/Mn on the Structure, Optical, and Electric Properties of PVC Polymer

Study of Commercial Additive Effects on the Poly(methyl methacrylate) Exposed to Gamma Irradiation by Viscosimetric Analysis

ZnS Nanoparticles‐decorated Composite Graphene Paper: A Novel Flexible Electrochemical Sensor for Detection of Dopamine

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