2024
DOI: 10.1002/pol.20240112
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Zwitterionic ring expansion polymerization of tert‐butyl glycidyl ether with B(C6F5)3 towards the generation of cyclic chains

Carlo Andrea Pagnacco,
Xuban Gastearena,
Estibaliz González de San Román
et al.

Abstract: The synthesis of cyclic polymers via zwitterionic ring expansion polymerization is limited to a few number of monomer and catalyst pairs. Herein we report the synthesis of cyclic poly(tert‐butyl glycidyl ether) through the polymerization of tert‐butyl glycidyl ether (tBGE) with B(C6F5)3 in different reaction conditions that include different solvents, monomer to initiator ratio, monomer concentration and temperature. We found that bimodal molecular weight distribution is formed in almost all reaction condition… Show more

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