2024
DOI: 10.1002/open.202400108
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α‐Halocarbonyls as a Valuable Functionalized Tertiary Alkyl Source

Takashi Nishikata

Abstract: This review introduces the synthetic organic chemical value of α‐bromocarbonyl compounds with tertiary carbons. This α‐bromocarbonyl compound with a tertiary carbon has been used primarily only as a radical initiator in atom transfer radical polymerization (ATRP) reactions. However, with the recent development of photo‐radical reactions (around 2010), research on the use of α‐bromocarbonyl compounds as tertiary alkyl radical precursors became popular (around 2012). As more examples were reported, α‐bromocarbon… Show more

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