Abstract. To quantify the contribution of new particle formation (NPF) to ultrafine
particle number and cloud condensation nuclei (CCN) budgets, one has to understand the mechanisms that
govern NPF in different environments and its temporal extent. Here, we study
NPF in Cyprus, an Eastern Mediterranean country located at the crossroads of
three continents and affected by diverse air masses originating from
continental, maritime, and desert-dust source areas. We performed 1-year
continuous measurements of aerosol particles down to ∼ 1 nm in
diameter for the first time in the Eastern Mediterranean and Middle East
(EMME) region. These measurements were complemented with trace gas data,
meteorological variables, and retroplume analysis. We show that NPF is a
very frequent phenomenon at this site and has higher frequencies of
occurrence during spring and autumn. NPF events were both of local and
regional origin, and the local events occurred frequently during the month
with the lowest NPF frequency. Some NPF events exhibited multiple onsets,
while others exhibited apparent particle shrinkage in size. Additionally,
NPF events were observed during the nighttime and during episodes of high
desert-dust loadings. Particle formation rates and growth rates were
comparable to those in urban environments, although our site is a rural one.
Meteorological variables and trace gases played a role in explaining the
intra-monthly variability of NPF events, but they did not explain why summer
months had the least NPF frequency. Similarly, pre-existing aerosol loading
did not explain the observed seasonality. The months with the least NPF
frequency were associated with higher H2SO4 concentrations but
lower NO2 concentrations, which is an indicator of anthropogenic
influence. Air masses arriving from the Middle East were not observed during
these months, which could suggest that precursor vapors important for
nucleation and growth are transported to our site from the Middle East.
Further comprehensive measurements of precursor vapors are required to prove
this hypothesis.
<p><strong>Abstract.</strong> Tropical peat-draining rivers are known as potentially large sources of carbon dioxide (CO<sub>2</sub>) to the atmosphere due to high loads of carbon they receive from surrounding soils. However, not many seasonally resolved data are available, limiting our understanding of these systems. We report the first measurements of carbon dioxide partial pressure (<i>p</i>CO<sub>2</sub>) in the Rajang River and Estuary, the longest river in Malaysia. The Rajang River catchment is characterized by extensive peat deposits found in the delta region, and by human impact such as logging, land use and river damming. <i>p</i>CO<sub>2</sub> averaged 2919&#8201;&#177;&#8201;573&#8201;&#181;atm during the wet season and 2732&#8201;&#177;&#8201;443&#8201;&#181;atm during the dry season. This is at the low end of reported values for Southeast Asian peat-draining rivers, but higher than values reported for Southeast Asian rivers that do not flow through peat deposits. However, dissolved inorganic carbon (DIC) and &#948;<sup>13</sup>C-DIC data did not suggest that peatlands were an important source of inorganic carbon to the river, with an average DIC concentration of 203.9&#8201;&#177;&#8201;59.6&#8201;&#181;mol&#8201;L<sup>&#8722;1</sup> and an average &#948;<sup>13</sup>C-DIC of &#8722;8.06&#8201;&#177;&#8201;1.90&#8201;&#8240;. Also, compared to rivers with similar peat coverage, the <i>p</i>CO<sub>2</sub> in the Rajang was rather low. Thus, we suggest that peat coverage is, by itself, insufficient as sole predictor of CO<sub>2</sub> emissions from peat-draining rivers, and that other factors, like the spatial distribution of peat in the catchment and pH, need to be considered as well. In the Rajang River, peatlands probably do not contribute much to the CO<sub>2</sub> flux due to the proximity of the peatlands to the coast. CO<sub>2</sub> fluxes to the atmosphere were 2.28&#8201;&#177;&#8201;0.52&#8201;gC&#8201;m<sup>&#8722;2</sup>&#8201;d<sup>&#8722;1</sup> (wet season) and 2.45&#8201;&#177;&#8201;0.45&#8201;gC&#8201;m<sup>&#8722;2</sup>&#8201;d<sup>&#8722;1</sup> (dry season), making the Rajang River a moderate source of carbon to the atmosphere.</p>
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