Large energy loss is one of the main limiting factors for power conversion efficiencies (PCEs) of organic solar cells (OSCs). To this effect, the chemical modifications of the famous Y‐series nonfullerene acceptor (NFA) BTP‐4Cl‐BO with a new end group, TPC‐Cl, whose π‐conjugation is extended through the fusing of 3‐(dicyanomethylene)indanone (IC) group with a chlorinated thiophene ring, to synthesize two novel NFAs, BTP‐T‐2Cl and BTP‐T‐3Cl are performed. For BTP‐T‐2Cl with two TPC‐Cl groups, the resulting OSC exhibits a modest PCE of 14.89% but an extraordinary low energy loss of 0.49 eV, because its superior electroluminescence quantum efficiency of 0.0606% mitigates significantly the nonradiative loss (0.191 eV). For BTP‐T‐3Cl with one TPC‐Cl group, the corresponding device shows a higher PCE of 17.61% accompanied by a slightly bigger energy loss of 0.51 eV, which can be ascribed to the optimized morphology and/or efficient charge generation. Furthermore, the ternary OSC adopting two NFAs of BTP‐T‐3Cl and BTP‐4Cl‐BO achieves an impressive PCE of 18.21% (certified value of 17.9%), which is among the highest values for OSCs to date. The above results demonstrate that expanding end groups of NFAs with electron‐donating rings is an effective strategy to realize lower energy losses for OSCs.

It has long been assumed that most parts of a genome and most genetic variations or SNPs are non-functional with regard to reproductive fitness. However, the collective effects of SNPs have yet to be examined by experimental science. We here developed a novel approach to examine the relationship between traits and the total amount of SNPs in panels of genetic reference populations. We identified the minor alleles (MAs) in each panel and the MA content (MAC) that each inbred strain carried for a set of SNPs with genotypes determined in these panels. MAC was nearly linearly linked to quantitative variations in numerous traits in model organisms, including life span, tumor susceptibility, learning and memory, sensitivity to alcohol and anti-psychotic drugs, and two correlated traits poor reproductive fitness and strong immunity. These results suggest that the collective effects of SNPs are functional and do affect reproductive fitness. collective effects, complex traits, minor alleles, SNPs, recombinant inbred lines, minor allele content (MAC) Citation:

We present optically derived estimates of phytoplankton carbon (Cphyto) and chlorophyll a concentration (Chl) across a wide range of productivity and hydrographic regimes in the Subarctic Pacific Ocean. Our high‐frequency measurements capture changes in Cphyto and Chl across regional gradients in macronutrient and micronutrient limitations and submesoscale hydrographic frontal zones. Throughout the majority of our survey region, carbon to chlorophyll ratios (Cphyto:Chl) ranged between 50 and 100. Lower values (10–20) were constrained to the highly productive coastal upwelling system along Vancouver Island, whereas higher estimated values (>200) were found directly off the southern British Columbia continental shelf. Further offshore, Cphyto:Chl was less variable, ranging from 50 to 80 in high nutrient low Chl waters in June and from 80 to 120 in the Gulf of Alaska in July. Much of the variability in Cphyto:Chl throughout the study region could be explained by mixed‐layer light levels (i.e., photoacclimation), with additional variability attributed to nutrient‐controlled changes in phytoplankton growth rates in some regions. Elevated Cphyto:Chl ratios resulting from apparent nutrient stress were found in areas of low macronutrient concentrations. In contrast, iron‐limited waters exhibited Cphyto:Chl ratios lower than predicted from the photoacclimation model. Applying the carbon‐based production model, we derived Cphyto and Chl‐based estimates of net primary productivity, which showed good coherence with independent 14C uptake measurements. Our results highlight the utility of ship‐board optical data to examine phytoplankton physiological ecology and productivity in surface marine waters.

Composed of shocked solar wind, the Earth's magnetosheath serves as a natural laboratory to study the transition of turbulence from low Alfvén Mach number, M A , to high M A. The simultaneous observations of magnetic field and plasma moments with unprecedented high temporal resolution provided by NASA's Magnetospheric Multiscale Mission (MMS) enable us to study the magnetosheath turbulence at both magnetohydrodynamics (MHD) and sub-ion scales. Based on 1841 burst-mode segments of MMS-1 from 2015 September to 2019 June, comprehensive patterns of the spatial evolution of magnetosheath turbulence are obtained: (1) from the subsolar region to the flanks, M A increases from <1 to >5. At MHD scales, the spectral indices of the magnetic-field and velocity spectra present a positive and negative correlation with M A. However, no obvious correlations between the spectral indices and M A are found at sub-ion scales. (2) From the bow shock to the magnetopause, the turbulent sonic Mach number, M turb , generally decreases from >0.4 to <0.1. All spectra steepen at MHD scales and flatten at sub-ion scales, representing positive/negative correlations with M turb. The break frequency increases by 0.1 Hz when approaching the magnetopause for the magnetic-field and velocity spectra, while it remains at 0.3 Hz for the density spectra. (3) In spite of minor differences, similar results are found for the quasi-parallel and quasi-perpendicular magnetosheath. In addition, such spatial evolution of magnetosheath turbulence is found to be independent of the upstream solar wind conditions, e.g., the averaged Z-component of the interplanetary magnetic field and solar wind speed.