Advance of photonics media is restrained by the lack of structuring techniques for the 3D fabrication of active materials with long‐range periodicity. A methodology is reported for the engineering of tunable resonant photonic media with thickness exceeding the plasmonic near‐field enhancement region by more than two orders of magnitude. The media architecture consists of a stochastically ordered distribution of plasmonic nanocrystals in a fractal scaffold of high‐index semiconductors. This plasmonic‐semiconductor fractal media supports the propagation of surface plasmons with drastically enhanced intensity over multiple length scales, overcoming the 2D limitations of established metasurface technologies. The fractal media are used for the fabrication of plasmonic optical gas sensors, achieving a limit of detection of 0.01 vol% at room temperature and sensitivity up to 1.9 nm vol%−1, demonstrating almost a fivefold increase with respect to an optimized planar geometry. Beneficially to their implementation, the self‐assembly mechanism of this fractal architecture allows fabrication of micrometer‐thick media over surfaces of several square centimeters in a few seconds. The designable optical features and intrinsic scalability of these photonic fractal metamaterials provide ample opportunities for applications, bridging across transformation optics, sensing, and light harvesting.
Introduction: X-ray computed tomography (CT) is now used in the cultural heritage field because it is non-invasive and it can give a large amount of information on the inner structure of the object under study. Until recently mainly medical CT scanners or micro-CT setups have been used, limiting the analysis to relatively small artworks or requiring multiple acquisition and difficult image-joining for objects larger than detector dimensions.
Introduction: X-ray imaging is a very powerful tool which can be exploited in several fields. In the last few years, its use in archaeology has grown consistently. One of the most recent and interesting applications of computed X-ray tomography (CT) is the analysis of soil blocks, coming from excavations, in order to seek for finds of different kinds and materials possibly contained therein. For this purpose, both medical and industrial CT scanners have been employed. In this paper, the application of a CT instrument specifically designed and developed for the analysis of Cultural Heritage materials is presented. We analysed a soil block extracted from a necropolis in the Italian region of Abruzzo and probably dating back to the VI-IV century B.C., which was found to contain a bronze belt. Results: Thanks to the versatility of the CT equipment we designed, a complete scan has been obtained in less than four hours and has delivered extremely useful information in a completely non-invasive way. The CT dataset and images allowed a virtual extraction of the find to be performed before the actual stratigraphic recovery that, in this case, was simplified thanks to the merging of the archaeological evidences and with information coming from scientific analyses. The information provided by the tomography consisted in: the distribution, shape and dimensions of fragments composing the artefact; indications about its general conditions; the recognition of repairs done in the past and the presence of different materials (although not precisely identified). Conclusions: The use of CT has great potential for the work of both archaeologists and restorers. The indirect extraction of an artefact from an archaeological excavation, which entailed moving a soil block to the laboratory, allowed one to reconstruct almost all its parts and to collect information about materials. CT analysis has been particularly useful for determining both its conditions and its repairs before the actual recovery, thereby facilitating the restoration process. The recovery and conservation of an historical piece like the one presented here can help archaeological and conservation studies, enrich a museum collection and contribute to the dissemination of acquired cultural information.
The Coptic textile collection of the Museo Egizio di Torino has been the object of a broad project aimed at investigating the production techniques, at documenting the conservation state and at reconsidering the attributed age. The collection was also analysed by non-invasive and micro-invasive techniques with the aim of detecting the dyes that have been employed to obtain the colours, in order to complete the set of technological information available for each textile. The data collected in the present work have been compared with published results from other Coptic textiles collections, with the aim of highlighting a possible link between age of the textile and the dyes that were employed. Moreover, the combined use of spectroscopic and chromatographic techniques allowed us to compare the results for the non-invasive and the micro-invasive approaches, and to go deeper into the dyeing technology by detecting unexpected combinations of dyes. In particular, the use of a double dyeing with madder and Indian lac dye was revealed in some Roman-Byzantine and Byzantine textiles.
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